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Amide nitrogen pyramidalization changes lactam amide spinning
Although cis-trans lactam amide rotation is fundamentally important, it has been little studied, except for a report on peptide-based lactams. Here, we find a consistent relationship between the lactam amide cis/trans ratios and the rotation rates between the trans and cis lactam amides upon the lac...
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| Publicado no: | Nat Commun |
|---|---|
| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group UK
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6349922/ https://ncbi.nlm.nih.gov/pubmed/30692534 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-08249-9 |
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