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Synthesis of the hitherto elusive formylphosphine (HCOPH(2)) in the interstellar medium - a molecule with an exotic phosphorus peptide bond

The formylphosphine (HCOPH(2)) molecule was detected in the gas phase via isomer selective photoionization reflectron time-of-flight mass spectrometry (PI-ReTOF-MS). Synthesized in carbon monoxide (CO)-phosphine ices (PH(3)) exposed to ionizing radiation, the formation mechanism involves an initial...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Frigge, Robert, Zhu, Cheng, Turner, Andrew M., Abplanalp, Matthew J., Sun, Bing-Jian, Huang, Ya-Syuan, Chang, Agnes H. H., Kaiser, Ralf I.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6340706/
https://ncbi.nlm.nih.gov/pubmed/30132473
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc04125c
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