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Cyclic tris-[5]helicenes with single and triple twisted Möbius topologies and Möbius aromaticity

A number of singly (180°) twisted, largely single-stranded and thus conformationally rather fragile, Möbius molecules have been synthesized within the last 15 years, which are aromatic with 4n electrons, thus violating the Hückel rule. Annulenes with significantly higher twist (e.g. 540°) that retai...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Naulet, Guillaume, Sturm, Ludmilla, Robert, Antoine, Dechambenoit, Pierre, Röhricht, Fynn, Herges, Rainer, Bock, Harald, Durola, Fabien
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6335628/
https://ncbi.nlm.nih.gov/pubmed/30746118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02877j
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