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Selective ring-opening metathesis polymerization (ROMP) of cyclobutenes. Unsymmetrical ladderphane containing polycyclobutene and polynorbornene strands

At 0 °C in THF in the presence of Grubbs first generation catalyst, cyclobutene derivatives undergo ROMP readily, whereas norbornene derivatives remain intact. When the substrate contains both cyclobutene and norbornene moieties, the conditions using THF as the solvent at 0 °C offer a useful protoco...

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Bibliografski detalji
Izdano u:Beilstein J Org Chem
Glavni autori: Ke, Yuan-Zhen, Huang, Shou-Ling, Lai, Guoqiao, Luh, Tien-Yau
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2019
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6334803/
https://ncbi.nlm.nih.gov/pubmed/30680037
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.4
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