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Selective ring-opening metathesis polymerization (ROMP) of cyclobutenes. Unsymmetrical ladderphane containing polycyclobutene and polynorbornene strands

At 0 °C in THF in the presence of Grubbs first generation catalyst, cyclobutene derivatives undergo ROMP readily, whereas norbornene derivatives remain intact. When the substrate contains both cyclobutene and norbornene moieties, the conditions using THF as the solvent at 0 °C offer a useful protoco...

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Bibliografske podrobnosti
izdano v:Beilstein J Org Chem
Main Authors: Ke, Yuan-Zhen, Huang, Shou-Ling, Lai, Guoqiao, Luh, Tien-Yau
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2019
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6334803/
https://ncbi.nlm.nih.gov/pubmed/30680037
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.4
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