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Formation of persistent organic diradicals from N,N′-diphenyl-3,7-diazacyclooctanes

ABSTRACT: N,N′-Diphenyl-3,7-diazacyclooctane and structurally related N,N′-diphenylbispidine derivatives react with silver(I) ions in a high-yielding C–C coupling reaction to produce dication–diradical species, with the silver ions serving a double function both as template and as an oxidant. The re...

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Detalhes bibliográficos
Publicado no:Monatsh Chem
Main Authors: Norrehed, Sara, Karlsson, Christoffer, Light, Mark E., Thapper, Anders, Huang, Ping, Gogoll, Adolf
Formato: Artigo
Idioma:Inglês
Publicado em: Springer Vienna 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6320754/
https://ncbi.nlm.nih.gov/pubmed/30679878
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-018-2298-4
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