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Cryostructuring of Polymeric Systems. 49. Unexpected “Kosmotropic-Like” Impact of Organic Chaotropes on Freeze–Thaw-Induced Gelation of PVA in DMSO

Urea (URE) and guanidine hydrochloride (GHC) possessing strong chaotropic properties in aqueous media were added to DMSO solutions of poly(vinyl alcohol) (PVA) to be gelled via freeze–thaw processing. Unexpectedly, it turned out that in the case of the PVA cryotropic gel formation in DMSO medium, th...

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Detalhes bibliográficos
Publicado no:Gels
Main Authors: Lozinsky, Vladimir I., Kolosova, Olga Yu., Michurov, Dmitrii A., Dubovik, Alexander S., Vasil’ev, Viktor G., Grinberg, Valerij Ya.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6318644/
https://ncbi.nlm.nih.gov/pubmed/30674857
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/gels4040081
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