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Total Synthesis of Terpenoids Employing a “Benzannulation of Carvone” Strategy: Synthesis of (−)-Crotogoudin

Carvone is a sustainable and readily available starting material for organic synthesis. Herein, we present the syntheses of various natural product scaffolds that rely on a novel benzannulation involving the α-methyl group (C-10) of carvone to afford a versatile tetralin. The utility of our syntheti...

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Publicado en:J Am Chem Soc
Main Authors: Finkbeiner, Peter, Murai, Kenichi, Röpke, Michael, Sarpong, Richmond
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6309435/
https://ncbi.nlm.nih.gov/pubmed/28763218
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b06823
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