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Shape-selective crystallisation of fluxional carbon cages
Dynamic covalent rearrangements of fluxional carbon cages, such as bullvalenes and barbaralanes, impart ‘shapeshifting’ molecular properties. Here, a series of five barbaralanes each interconvert dynamically between two constitutional isomers in solution, but resolve to single isomers upon crystalli...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6301275/ https://ncbi.nlm.nih.gov/pubmed/30647882 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04303e |
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