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Ir(iii)-catalyzed ortho C–H alkylations of (hetero)aromatic aldehydes using alkyl boron reagents

Transition-metal-catalyzed C–H alkylation reactions directed by aldehydes or ketones have been largely restricted to electronically activated alkenes. Herein, we report a general protocol for the Ir(iii)-catalyzed ortho C–H alkylations of (hetero)aromatic aldehydes using alkyl boron reagents as the...

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Pubblicato in:Chem Sci
Autori principali: Chen, Xiao-Yang, Sorensen, Erik J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6301268/
https://ncbi.nlm.nih.gov/pubmed/30647887
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03606c
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