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Stibine-protected Au(13) nanoclusters: syntheses, properties and facile conversion to GSH-protected Au(25) nanocluster
Monostibine-protected ionic Au(13) nanoclusters, namely, [Au(13)(L)(8)(Cl)(4)][Cl] (L= SbPh(3), 2a·Cl; Sb(p-tolyl)(3), 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH(4) in dichloromethane. Anion exchange with 2a·Cl afforded [Au(13)(SbPh(3))(8)(Cl)(4)][X] (X = PF(6), 2a·PF(6); BPh(...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6289101/ https://ncbi.nlm.nih.gov/pubmed/30627392 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03132k |
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