Conversion of Medium-Sized Lactams to α-Vinyl or α-Acetylenyl Azacycles via N,O-Acetal TMS Ethers

α-Vinyl or α-acetylenyl azacycles were easily synthesized from 7- to 9-membered lactams and 6- to 9-membered lactams via N,O-acetal trimethylsilyl (TMS) ethers. Organocopper and organostannane reagents afforded reasonable yields for the respective N-acyliminium ion vinylation and acetylenylation int...

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Publicado no:Molecules
Main Authors: Kim, Minjun, Jang, Jaebong, Choi, Goyoung, Chung, Sungkyun, Lim, Changjin, Hur, Joonseong, Kim, Hyun Su, Na, Younghwa, Son, Woo Sung, Suh, Young-Ger, Jung, Jong-Wha, Kim, Seok-Ho
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2018
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6278647/
https://ncbi.nlm.nih.gov/pubmed/30463260
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules23113023
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