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A Computational Study of the Mechanism of Succinimide Formation in the Asn–His Sequence: Intramolecular Catalysis by the His Side Chain

The rates of deamidation reactions of asparagine (Asn) residues which occur spontaneously and nonenzymatically in peptides and proteins via the succinimide intermediate are known to be strongly dependent on the nature of the following residue on the carboxyl side (Xxx). The formation of the succinim...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Takahashi, Ohgi, Manabe, Noriyoshi, Kirikoshi, Ryota
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6274526/
https://ncbi.nlm.nih.gov/pubmed/27005609
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21030327
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