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Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems
A study was undertaken of the solvolysis of pivaloyl triflate in a variety of ionic liquid:alcohol solvent mixtures. The solvolysis is a k(Δ) process (i.e., a process in which ionization occurs with rearrangement), and the resulting rearranged carbocation intermediate reacts with the alcohol cosolve...
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| Publié dans: | Molecules |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
MDPI
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6273061/ https://ncbi.nlm.nih.gov/pubmed/26751434 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21010060 |
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