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TBD- or PS-TBD-Catalyzed One-Pot Synthesis of Cyanohydrin Carbonates and Cyanohydrin Acetates from Carbonyl Compounds

Cyanation reactions of carbonyl compounds with methyl cyanoformate or acetyl cyanide catalyzed by 5 mol % of 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TBD) were examined. Using methyl cyanoformate, the corresponding cyanohydrin carbonates were readily obtained in high yield for aromatic and aliphatic ald...

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Publicat a:Molecules
Autors principals: Matsukawa, Satoru, Kimura, Junya, Yoshioka, Miki
Format: Artigo
Idioma:Inglês
Publicat: MDPI 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6273017/
https://ncbi.nlm.nih.gov/pubmed/27517899
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21081030
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