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Organocatalyzed Intramolecular Carbonyl-Ene Reactions

An organocatalyzed intramolecular carbonyl-ene reaction was developed to produce carbocyclic and heterocyclic 5- and 6-membered rings from a citronellal-derived trifluoroketone and a variety of aldehydes. A phosphoramide derivative was found to promote the cyclization of the trifluoroketone, whereas...

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Bibliographic Details
Published in:Molecules
Main Authors: Dahlmann, Heidi A., McKinney, Amanda J., Santos, Maria P., Davis, Lindsey O.
Format: Artigo
Language:Inglês
Published: MDPI 2016
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6272844/
https://ncbi.nlm.nih.gov/pubmed/27258238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21060713
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