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Chiroptical Properties and the Racemization of Pyrene and Tetrathiafulvalene-Substituted Allene: Substitution and Solvent Effects on Racemization in Tetrathiafulvalenylallene

Dissymmetric 1,3-diphenylallene derivative 3 connected with 4,5-bis(methyl-thio)tetrathiafulvalenyl and 1-pyrenyl substituents was prepared and characterized. The molecular structure was determined by X-ray crystallographic analysis. Optical resolution was accomplished using a recycling chiral HPLC,...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Hasegawa, Masashi, Iwata, Seiya, Sone, Yasuto, Endo, Junta, Matsuzawa, Hideyo, Mazaki, Yasuhiro
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6271782/
https://ncbi.nlm.nih.gov/pubmed/24599123
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules19032829
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