Yüklüyor......
Dissociation of the Disilatricyclic Diallylic Dianion [(C(4)Ph(4)SiMe)(2)](−2) to the Silole Anion [MeSiC(4)Ph(4)](−) by Halide Ion Coordination or Halide Ion Nucleophilic Substitution at the Silicon Atom
The reductive cleavage of the Si-Si bond in 1,1-bis(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene) [(C(4)Ph(4)SiMe)(2)] (1) with either Li or Na in THF gives the silole anion [MeSiC(4)Ph(4)](−) (2). The head-to-tail dimerization of the silole anion 2 gives crystals of the disilatricyclic dially...
Kaydedildi:
| Yayımlandı: | Molecules |
|---|---|
| Yazar: | |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
MDPI
2011
|
| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6264495/ https://ncbi.nlm.nih.gov/pubmed/21986523 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules16108451 |
| Etiketler: |
Etiketle
Etiket eklenmemiş, İlk siz ekleyin!
|