Enhanced Reactivity of [Hydroxy(tosyloxy)iodo]benzene in Fluoroalcohol Media. Efficient Direct Synthesis of Thienyl(aryl)iodonium Salts

In this manuscript, we report clear evidence for the generation of aromatic cation radicals produced by using [hydroxy(tosyloxy)iodo]benzene (HTIB) in fluoroalcohol solvents such as 2,2,2-trifluoroethanol (TFE) and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP). The single-electron-transfer (SET) oxidatio...

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Bibliographic Details
Published in:Molecules
Main Authors: Ito, Motoki, Ogawa, Chieko, Yamaoka, Nobutaka, Fujioka, Hiromichi, Dohi, Toshifumi, Kita, Yasuyuki
Format: Artigo
Language:Inglês
Published: Molecular Diversity Preservation International 2010
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6257409/
https://ncbi.nlm.nih.gov/pubmed/20336022
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules15031918
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