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High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium(iii) metallocenium single-molecule magnets

A series of dysprosium(iii) metallocenium salts, [Dy(Cp(iPr4R))(2)][B(C(6)F(5))(4)] (R = H (1), Me (2), Et (3), iPr (4)), was synthesized by reaction of DyI(3) with the corresponding known NaCp(iPr4R) (R = H, iPr) and novel NaCp(iPr4R) (R = Me, Et) salts at high temperature, followed by iodide abstr...

Ausführliche Beschreibung

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Veröffentlicht in:Chem Sci
Hauptverfasser: Randall McClain, K., Gould, Colin A., Chakarawet, Khetpakorn, Teat, Simon J., Groshens, Thomas J., Long, Jeffrey R., Harvey, Benjamin G.
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2018
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6256727/
https://ncbi.nlm.nih.gov/pubmed/30568773
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03907k
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