Direct synthesis of aryl-annulated [c]carbazoles by gold(i)-catalysed cascade reaction of azide-diynes and arenes

The gold-catalysed annulation of conjugated alkynes bearing an azido group with arenes gave annulated [c]carbazoles. Using benzene, pyrrole, and indole derivatives as the nucleophiles, benzo[c]-, pyrrolo[2,3-c]-, and indolo[2,3-c]carbazoles were produced, respectively. The reaction proceeded through...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Kawada, Yuiki, Ohmura, Shunsuke, Kobayashi, Misaki, Nojo, Wataru, Kondo, Masaki, Matsuda, Yuka, Matsuoka, Junpei, Inuki, Shinsuke, Oishi, Shinya, Wang, Chao, Saito, Tatsuo, Uchiyama, Masanobu, Suzuki, Takanori, Ohno, Hiroaki
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6244455/
https://ncbi.nlm.nih.gov/pubmed/30542591
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03525c
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