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Twist sense control in terminally functionalized ortho-phenylenes

Many abiotic foldamers are based on achiral repeat units but adopt chiral geometries, especially helices. In these systems, there is no inherent preference for one handedness of the fold; however, it is well-established that the point chirality of substituents can be communicated to the helix. This...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Vemuri, Gopi Nath, Pandian, Rathiesh R., Spinello, Brian J., Stopler, Erika B., Kinney, Zacharias J., Hartley, C. Scott
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2018
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6240895/
https://ncbi.nlm.nih.gov/pubmed/30542575
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02821d
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