Structure-switching M(3)L(2) Ir(iii) coordination cages with photo-isomerising azo-aromatic linkers

Cyclotriguaiacylene has been functionalised with 3- or 4-pyridyl-azo-phenyl groups to form a series of molecular hosts with three azobenzene-type groups that exhibit reversible photo-isomerisation. Reaction of the host molecules with [Ir(C^N)(2)(NCMe)(2)](+) where C^N is the cyclometallating 2-pheny...

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Udgivet i:Chem Sci
Main Authors: Oldknow, Samuel, Martir, Diego Rota, Pritchard, Victoria E., Blitz, Mark A., Fishwick, Colin W. G., Zysman-Colman, Eli, Hardie, Michaele J.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2018
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6238882/
https://ncbi.nlm.nih.gov/pubmed/30542566
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03499k
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