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Reversible coordination of N(2) and H(2) to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state
The synthesis and characterisation of the S = 1/2 Fe(i) complex [Fe(depe)(2)](+)[BArF4](–) ([1](+)[BArF4](–)), and the facile reversible binding of N(2) and H(2) in both solution and the solid state to form the adducts [1·N(2)](+) and [1·H(2)](+), are reported. Coordination of N(2) in THF is thermod...
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| Опубликовано в: : | Chem Sci |
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| Главные авторы: | , , , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Royal Society of Chemistry
2018
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6237127/ https://ncbi.nlm.nih.gov/pubmed/30542539 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01841c |
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