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Thermal Rearrangement of Allyl Substituted Unsymmetric 4H-1,2,4-Triazoles to the Corresponding 1H-1,2,4-triazoles.

A series of neat 4-(2-alkenyl) substituted 5-methyl-3-phenyl-4H-1,2,4-triazoles were thermolyzed at 320 °C producing a rearrangement products, of which the regioisomeric 1- and 2-substituted triazoles were the main products. The group migrations were rationalized in terms of consecutive S(N)2-type r...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Jørgensen, Kåre B., Olsen, Ragnhild B., Carlsen, Per H.J.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2001
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6236431/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/60500481
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