Tunneling Probability Increases with Distance in Junctions Comprising Self-Assembled Monolayers of Oligothiophenes

[Image: see text] Molecular tunneling junctions should enable the tailoring of charge-transport at the quantum level through synthetic chemistry but are hindered by the dominance of the electrodes. We show that the frontier orbitals of molecules can be decoupled from the electrodes, preserving their...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Zhang, Yanxi, Soni, Saurabh, Krijger, Theodorus L., Gordiichuk, Pavlo, Qiu, Xinkai, Ye, Gang, Jonkman, Harry T., Herrmann, Andreas, Zojer, Karin, Zojer, Egbert, Chiechi, Ryan C.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2018
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6225337/
https://ncbi.nlm.nih.gov/pubmed/30359013
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b09793
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