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Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming

C‐saturated Pd(0) nanoparticles with an extended phase boundary to ZrO(2) evolve from a Pd(0)Zr(0) precatalyst under CH(4) dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO(2) is efficiently activated at oxidic phase boundary sites and Pd(x)C provides fast s...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Köpfle, Norbert, Götsch, Thomas, Grünbacher, Matthias, Carbonio, Emilia A., Hävecker, Michael, Knop‐Gericke, Axel, Schlicker, Lukas, Doran, Andrew, Kober, Delf, Gurlo, Aleksander, Penner, Simon, Klötzer, Bernhard
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2018
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6221108/
https://ncbi.nlm.nih.gov/pubmed/30179293
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807463
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