Total Synthesis, Stereochemical Assignment, and Divergent Enantioselective Enzymatic Recognition of Larreatricin

A concise and efficient total synthesis of the lignan natural product larreatricin as well as an unambiguous assignment of configuration of its enantiomers are reported, resolving a long‐held controversy. Enzyme kinetic studies revealed that different polyphenol oxidases show high and remarkably div...

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Опубликовано в: :Chemistry
Главные авторы: Martin, Harry J., Kampatsikas, Ioannis, Oost, Rik, Pretzler, Matthias, Al‐Sayed, Emir, Roller, Alexander, Giester, Gerald, Rompel, Annette, Maulide, Nuno
Формат: Artigo
Язык:Inglês
Опубликовано: John Wiley and Sons Inc. 2018
Предметы:
Communications
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6220842/
https://ncbi.nlm.nih.gov/pubmed/30113748
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201803785
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