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Synthesis and structural characterization of four di­chlorido­bis­(cyclo­propyl­alkynyl­amidine)­metal complexes

Deliberate hydrolysis of lithium cyclo­propyl­alkynylamidinates, Li[c-C(3)H(5)—C≡C(NR′)(2)] [R′ = (i)Pr, Cy = cyclo­hex­yl)], afforded the hitherto unknown neutral cyclo­propyl­alkynyl­amidine derivatives c-C(3)H(5)—C≡C—C(NR′)(NHR′) [R′ = (i)Pr (1), Cy (2)]. Subsequent reactions of 1 or 2 with metal...

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Bibliographic Details
Published in:Acta Crystallogr E Crystallogr Commun
Main Authors: Wang, Sida, Liebing, Phil, Engelhardt, Felix, Hilfert, Liane, Busse, Sabine, Edelmann, Frank T.
Format: Artigo
Language:Inglês
Published: International Union of Crystallography 2018
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6218897/
https://ncbi.nlm.nih.gov/pubmed/30443401
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989018014895
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