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Energy Relaxation and Structural Dynamics of Protons in Water/DMSO Mixtures

[Image: see text] We investigate the structure and dynamics of proton solvation structures in mixed water/dimethyl sulfoxide (DMSO) solvents using two-color mid-infrared femtosecond pump–probe spectroscopy. At a water fraction below 20%, protons are mainly solvated as (DMSO-H)(+) and (DMSO-H)(+)-H(2...

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Publicado en:J Phys Chem B
Main Authors: Sofronov, Oleksandr O., Bakker, Huib J.
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2018
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6216113/
https://ncbi.nlm.nih.gov/pubmed/30351147
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.8b06938
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