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Reduction and Condensation of Aldehydes by the Isolated Cofactor of Nitrogenase

[Image: see text] Isolated nitrogenase cofactors can reduce CO, CN(–), and CO(2) to short-chain hydrocarbons in reactions driven by a strong reductant. Here, we use activity analyses and isotope labeling experiments to show that formaldehyde and acetaldehydes can be reduced as-is or reductively cond...

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Bibliographic Details
Published in:ACS Cent Sci
Main Authors: Lee, Chi Chung, Hu, Yilin, Ribbe, Markus W.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2018
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6202647/
https://ncbi.nlm.nih.gov/pubmed/30410981
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.8b00553
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