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Biosynthesis of the Thiopeptins and Identification of an F(420)H(2)-Dependent Dehydropiperidine Reductase

Thiopeptins are highly decorated thiopeptide antibiotics similar in structure to thiostrepton A and harbor two unusual features. All thiopeptins contain a thioamide, a rare moiety among natural products, and a subset of thiopeptins present with a piperidine in the core macrocycle rather than the mor...

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Publicado en:J Am Chem Soc
Autores principales: Ichikawa, Hiro, Bashiri, Ghader, Kelly, Wendy L.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2018
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6193465/
https://ncbi.nlm.nih.gov/pubmed/30118217
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b04238
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