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Transformation of alcohols to esters promoted by hydrogen bonds using oxygen as the oxidant under metal-free conditions

One-pot oxidative transformation of alcohols into esters is very attractive, but metal-based catalysts are used in the reported routes. We discovered that the basic ionic liquid 1-ethyl-3-methylimidazolium acetate ([EMIM] OAc) could effectively catalyze this kind of reaction using O(2) as an oxidant...

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Detalhes bibliográficos
Publicado no:Sci Adv
Main Authors: Liu, Mingyang, Zhang, Zhanrong, Liu, Huizhen, Xie, Zhenbing, Mei, Qingqing, Han, Buxing
Formato: Artigo
Idioma:Inglês
Publicado em: American Association for the Advancement of Science 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6173529/
https://ncbi.nlm.nih.gov/pubmed/30310866
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.aas9319
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