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Palladium/Rhodium Cooperative Catalysis for the Production of Aryl Aldehydes and Their Deuterated Analogues Using the Water–Gas Shift Reaction

A novel Pd/Rh dual-metallic cooperative catalytic process has been developed to effect the reductive carbon-ylation of aryl halides in moderate to good yield. In this reaction, water is the hydride source, and CO serves both as the carbonyl source and the terminal reductant through the water-gas shi...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Ibrahim, Malek Y. S., Denmark, Scott E.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6173325/
https://ncbi.nlm.nih.gov/pubmed/30015402
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201806148
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