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Enantioselective counter-anions in photoredox catalysis: the asymmetric cation radical Diels-Alder reaction
Control of absolute stereochemistry in radical and ion radical transformations is a major challenge in synthetic chemistry. Herein, we report the design of a photoredox catalyst system comprised of an oxidizing pyrilium salt bearing a chiral N-triflyl phosphoramide anion. This class of chiral organi...
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| Udgivet i: | Tetrahedron |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6166882/ https://ncbi.nlm.nih.gov/pubmed/30287974 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2018.03.052 |
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