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Enantioselective counter-anions in photoredox catalysis: the asymmetric cation radical Diels-Alder reaction

Control of absolute stereochemistry in radical and ion radical transformations is a major challenge in synthetic chemistry. Herein, we report the design of a photoredox catalyst system comprised of an oxidizing pyrilium salt bearing a chiral N-triflyl phosphoramide anion. This class of chiral organi...

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Detaylı Bibliyografya
Yayımlandı:Tetrahedron
Asıl Yazarlar: Morse, Peter D., Nguyen, Tien M., Cruz, Cole L., Nicewicz, David A.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2018
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6166882/
https://ncbi.nlm.nih.gov/pubmed/30287974
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2018.03.052
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