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Theoretical Investigation of the Hydrolytic Mechanism of α-Functionalized Alkoxysilanes as Effective Crosslinkers and the Difficulty of Deep Vulcanization in RTV Silicone Rubber

The reactions between α-, γ-ethylenediaminemethyl trimethyl-ketoxime silane (α-, γ-EAMOS) and H(2)O were investigated on the geometries of stationary points, the reaction pathway (IRC), thermodynamic and kinetic analysis by density functional theory (DFT) at the B3LYP/6-311G (d, p) level. Interestin...

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Detaylı Bibliyografya
Yayımlandı:Materials (Basel)
Asıl Yazarlar: Xu, Huihui, Gao, Yanhong, Liu, Zihou, Bei, Yiling
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: MDPI 2018
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6163510/
https://ncbi.nlm.nih.gov/pubmed/30149562
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma11091526
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