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Identifying the missing link in catalyst transfer polymerization

Nickel-catalyzed catalyst transfer polycondensation (CTP) of thiophenes is an efficient strategy for the controlled synthesis of polythiophenes. However, a detailed view of its reaction mechanism has remained elusive with unresolved questions regarding the geometry and bonding of critical Ni(0) thio...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: He, Weiying, Patrick, Brian O., Kennepohl, Pierre
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6155128/
https://ncbi.nlm.nih.gov/pubmed/30250037
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-06324-9
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