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Metal-Mediated Addition of N-Nucleophiles to Isocyanides: Mechanistic Aspects

Despite the long history of the investigation of nucleophilic addition to metal-bound isocyanides, some important aspects of the reaction mechanism remain unclear even for the simplest systems. In this work, the addition of the sp(3)-N, sp(2)-N, and mixed sp(2)/sp(3)-N nucleophiles (i.e., HNMe(2), H...

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Bibliographic Details
Published in:Molecules
Main Authors: Kuznetsov, Maxim L., Kukushkin, Vadim Yu.
Format: Artigo
Language:Inglês
Published: MDPI 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6152363/
https://ncbi.nlm.nih.gov/pubmed/28698454
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules22071141
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