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Readily Available Chiral Benzimidazoles-Derived Guanidines as Organocatalysts in the Asymmetric α-Amination of 1,3-Dicarbonyl Compounds

The synthesis and the evaluation as organocatalysts of new chiral guanidines derived from benzimidazoles in the enantioselective α-amination of 1,3-dicarbonyl compounds using di-t-butylazodicarboxylate as aminating agent is herein disclosed. The catalysts are readily synthesized through the reaction...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Benavent, Llorenç, Puccetti, Francesco, Baeza, Alejandro, Gómez-Martínez, Melania
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6152235/
https://ncbi.nlm.nih.gov/pubmed/28800100
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules22081333
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