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Halogen Bonds Formed between Substituted Imidazoliums and N Bases of Varying N-Hybridization

Heterodimers are constructed containing imidazolium and its halogen-substituted derivatives as Lewis acid. N in its sp(3), sp(2) and sp hybridizations is taken as the electron-donating base. The halogen bond is strengthened in the Cl < Br < I order, with the H-bond generally similar in magnitu...

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Vydáno v:Molecules
Hlavní autor: Scheiner, Steve
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2017
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6151534/
https://ncbi.nlm.nih.gov/pubmed/28961202
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules22101634
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