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Effect of Step Density and Orientation on the Apparent pH Dependence of Hydrogen and Hydroxide Adsorption on Stepped Platinum Surfaces

[Image: see text] The effect of the alkali-metal cation (Li(+), Na(+), K(+), and Cs(+)) on the non-Nernstian pH shift of the Pt(554) and Pt(533) step-associated voltammetric peak is elucidated over a wide pH window (1–13), through computation and experiment. In conjunction with our previously report...

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Detalhes bibliográficos
Publicado no:J Phys Chem C Nanomater Interfaces
Main Authors: McCrum, Ian T., Chen, Xiaoting, Schwarz, Kathleen A., Janik, Michael J., Koper, Marc T. M.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2018
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6150671/
https://ncbi.nlm.nih.gov/pubmed/30258524
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcc.8b03660
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