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(19)F-NMR Diastereotopic Signals in Two N-CHF(2) Derivatives of (4S,7R)-7,8,8-Trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-indazole †

In this paper, we report the anisochrony of the fluorine atoms of a CHF(2) group when linked to a pyrazole ring. The pyrazole is part of (4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-indazole also known as (4S,7R)-campho[2,3-c]pyrazole, which has two stereogenic centers. Gauge-Independen...

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Detalles Bibliográficos
Publicado en:Molecules
Main Authors: García-Pérez, Diana, López, Concepción, Claramunt, Rosa M., Alkorta, Ibon, Elguero, José
Formato: Artigo
Idioma:Inglês
Publicado: MDPI 2017
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6150283/
https://ncbi.nlm.nih.gov/pubmed/29149081
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules22112003
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