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Unusual Reactivity Patterns of 1,3,6,8-Tetraazatricyclo-[4.4.1.1(3,8)]-dodecane (TATD) Towards Some Reducing Agents: Synthesis of TMEDA
N,N,N´,N´-Tetramethylethylenediamine (TMEDA) can be synthesized by simple reduction of 1,3,6,8-tetraazatricyclo-[4.4.1.1.(3,8)]dodecane (TATD), an aminal cage type amine, with formic acid. The aminal can be converted to TMEDA in high yield very easily and in a very short time. We comment on the scop...
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| Publicado no: | Molecules |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6149478/ https://ncbi.nlm.nih.gov/pubmed/17909502 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/12071471 |
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