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Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.

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Bibliographic Details
Published in:Molecules
Main Authors: Luo, Shengj-Jun, Ma, Yong-Xiang, Liang, Yong-Min
Format: Artigo
Language:Inglês
Published: MDPI 2005
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6147542/
https://ncbi.nlm.nih.gov/pubmed/18007291
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/10010238
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