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The Effects of Conjugation Path Variation on Electron Delocalization in Phenoxyl-Based Systems

A number of persistent 2,6-di-tert-butylphenoxyl based radicals were synthesized as models for unpaired spin delocalization as a function of conjugation pathway, and were investigated by ESR and UV-vis spectroscopy. Phenoxyl spin delocalizes significantly onto a para-phenyl ring, but further delocal...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Liu, Yanbing, Lahti, Paul M.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2004
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6147353/
https://ncbi.nlm.nih.gov/pubmed/18007473
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/90900725
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