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Synthesis of 5-Methylene-2-pyrrolones

A facile, one-pot synthetic method for the synthesis of 5-methylene-2-pyrrolones (5MPs) from inexpensive furfuryl acetate is described. Bromine oxidation and trapping of the in situ generated 1,4-dicarbonyl compound by a primary amine provided the corresponding 5MPs in 50–69% yield.

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Jacinto, Marco Paolo, Pichling, Patricio, Greenberg, Marc M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6132240/
https://ncbi.nlm.nih.gov/pubmed/30063360
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02030
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