Probing the oxidation state of transition metal complexes: a case study on how charge and spin densities determine Mn L-edge X-ray absorption energies

Transition metals in inorganic systems and metalloproteins can occur in different oxidation states, which makes them ideal redox-active catalysts. To gain a mechanistic understanding of the catalytic reactions, knowledge of the oxidation state of the active metals, ideally in operando, is therefore...

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書誌詳細
出版年:Chem Sci
主要な著者: Kubin, Markus, Guo, Meiyuan, Kroll, Thomas, Löchel, Heike, Källman, Erik, Baker, Michael L., Mitzner, Rolf, Gul, Sheraz, Kern, Jan, Föhlisch, Alexander, Erko, Alexei, Bergmann, Uwe, Yachandra, Vittal, Yano, Junko, Lundberg, Marcus, Wernet, Philippe
フォーマット: Artigo
言語:Inglês
出版事項: Royal Society of Chemistry 2018
主題:
Chemistry
オンライン･アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6115617/
https://ncbi.nlm.nih.gov/pubmed/30310614
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00550h
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