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Comparison between Tetrel Bonded Complexes Stabilized by σ and π Hole Interactions

The σ-hole tetrel bonds formed by a tetravalent molecule are compared with those involving a π-hole above the tetrel atom in a trivalent bonding situation. The former are modeled by TH(4), TH(3)F, and TH(2)F(2) (T = Si, Ge, Sn) and the latter by TH(2)=CH(2), THF=CH(2), and TF(2)=CH(2), all paired wi...

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Publicat a:Molecules
Autors principals: Zierkiewicz, Wiktor, Michalczyk, Mariusz, Scheiner, Steve
Format: Artigo
Idioma:Inglês
Publicat: MDPI 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6100375/
https://ncbi.nlm.nih.gov/pubmed/29891824
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules23061416
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