Bench‐Stable N‐Heterocyclic Carbene Nickel Precatalysts for C−C and C−N Bond‐Forming Reactions

Herein, we introduce a new class of bench‐stable N‐heterocyclic carbene (NHC) nickel‐precatalysts for homogeneous nickel‐catalysis. The nickel(II) complexes are readily activated to Ni(0) in situ under mild conditions, via a proposed Heck‐type mechanism. The precatalysts are shown to facilitate carb...

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Foilsithe in:ChemCatChem
Main Authors: Strieth‐Kalthoff, Felix, Longstreet, Ashley R., Weber, Jessica M., Jamison, Timothy F.
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2018
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Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6099443/
https://ncbi.nlm.nih.gov/pubmed/30147804
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201800454
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