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Securing a Supramolecular Architecture by Tying a Stopper Knot

We report on a rotaxane‐like architecture secured by the in situ tying of an overhand knot in the tris(2,6‐pyridyldicarboxamide) region of the axle through complexation with a lanthanide ion (Lu(3+)). The increase in steric bulk caused by the knotting locks a crown ether onto the thread. Removal of...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Leigh, David A., Pirvu, Lucian, Schaufelberger, Fredrik, Tetlow, Daniel J., Zhang, Liang
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6099318/
https://ncbi.nlm.nih.gov/pubmed/29708636
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201803871
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