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Photoredox Cyanomethylation of Indoles: Catalyst Modification and Mechanism
The direct cyanomethylation of indoles at the 2- or 3-position was achieved via photoredox catalysis. The versatile nitrile synthon is introduced as a radical generated from bromoacetonitrile, a photocatalyst, and blue LEDs as a light source. The mechanism of the reaction is explored by determinatio...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6097937/ https://ncbi.nlm.nih.gov/pubmed/29940725 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b01146 |
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